Cycle life
Conditions, retention, and degradation mechanisms.
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Conditions, retention, and degradation mechanisms.
Section 01
Cycle count alone has no complete meaning; rate, temperature, SOC window, rest, cutoffs, and retention definition are required. If protocol changes, reported life may not be directly comparable even when the cell is unchanged.
—State cycling window
—State end-of-life criterion
—State sample count and variation
Section 02
Capacity loss and impedance rise can arise from side reactions, active-material change, contact loss, sodium-inventory imbalance, manufacturing defect, or thermal stress. Diagnosis should combine electrochemistry, teardown, controls, and production traceability rather than infer one root cause from one symptom.
—Observe capacity and impedance together
—Validate material and process separately
—Controls support causal inference
Section 03
Storage dispatch, start-stop pulses, and telecom backup differ in temperature, depth of discharge, rest, and power requirements. Application-life assessment should use representative duty cycles and include maintenance, BMS control, and system thermal conditions.
—DOD affects accumulated stress
—Temperature affects reactions and transport
—System control affects usable window
Vocabulary
Learning path