Rate capability
Charge/discharge rates, polarization, and heat.
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Charge/discharge rates, polarization, and heat.
Section 01
C-rate or another rate label must use a stated capacity basis and protocol. If basis, temperature, cutoffs, or sample state differ, two tests with the same label may not be comparable, so figures need complete annotations.
—State capacity basis
—State charge or discharge direction
—State temperature and cutoffs
Section 02
At higher current, ion movement in electrolyte and pores, electron transport in conductive networks, and interfacial charge transfer can all limit performance. Thicker or more compacted electrodes can also amplify local concentration and temperature differences.
—Ion path depends on porosity
—Electron path depends on conductive network
—Interphase path depends on reaction kinetics
Section 03
Start-stop, short-duration UPS, and sustained storage demand different pulse and continuous power. Selection should assess usable energy, heat, efficiency, and cycling cost together rather than using one short pulse result as a substitute for sustained operation.
—Pulse and continuous power differ
—Heat affects system conditions
—Efficiency affects deliverable energy
Vocabulary
Learning path